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Saghafi H. Fe (II) Immobilized on Activated Carbon Surface as a Catalyst for elimination of Alizarin Red S at the Presence of Hydrogen Peroxide. sjfst 2024; 6 (1) :1-7
URL: http://sjfst.srpub.org/article-6-134-en.html
Fe (II) Immobilized on Activated Carbon Surface as a Catalyst for elimination of Alizarin Red S at the Presence of Hydrogen Peroxide
Hamzeh Saghafi *
MSc of applied chemistry, Department of chemistry, Semnan University, Semnan, Iran.
Abstract:   (142 Views)
In this study, removal of Alizarin red S(ARS) in aqueous solutions by oxidation process, using hydrogen peroxide(H2O2)and Fe(II) immobilized on activated carbon (AC) surface (Fe(II)/AC) as catalyst, was studied. In this case, the combination of catalyst and hydrogen peroxide significantly enhanced the removal process. The effects of pH, H2O2 and catalyst dosage, temperature and ARS concentration were also studied. The optimum conditions for ARS removal were obtained at pH=5, 2.5mL of 30% H2O2, 0.125gr of catalyst at 328K and 1×10-2M of ARS concentration. In the optimum condition 99% of ARS was removed after 30min of reaction This work is considered as a suitable method for removal of high concentration of ARS in aqueous media.                                                                                           
Keywords: Removal, ARS, Catalyst, H2O2, Hydroxyl Radical
Full-Text [PDF 388 kb]   (6 Downloads)    
Type of Study: Research | Subject: Process Chemistry and Technology
Received: 2023/11/27 | Revised: 2024/02/25 | Accepted: 2024/03/15 | Published: 2024/03/25
References
1. Muhammad Ahmad, Misbahul Ain Khan, Umar Farooq, Makshoof Athar, (2012). Carbonized green tea dredge, a potential adsorbent for removal of remazol brilliant yellow dye, J. Mater. Environ. Sci. 3 (1): 149-156.
2. Abdul Latif Ahmad, Wan Azlina Harris, Syafiie, Ooi Boon Seng, (2002). Removal of dye from wastewater of textile industry using membrane technology, Journal Teknologi 36(F): 31-44. [DOI:10.11113/jt.v36.581]
3. Rabia Rehman, Tariq Mahmud, Jamil Anwar, Muhammad Salman, Umer Shafique, Waheed-UZ-Zaman, Furqan Ali, (2011). Removal of Alizarin Red S (Dye) from aqueous media by using alumina as an adsorbent, J.Chem.Soc.Pak., 33 (2), 228- 232.
4. Nevine Kamal Amin, (2008). Removal of reactive dye from aqueous solutions by adsorption onto activated carbons prepared from sugarcane bagasse pith, Desalination, 223, 1-3: 152-161. [DOI:10.1016/j.desal.2007.01.203]
5. Wen-Hong Li, Qin-Yan Yue, Bao-Yu Gao, Zuo-Hao Ma, Yan-Jie Li, Hai-Xia Zhao, (2011). Preparation and utilization of sludge-based activated carbon for the adsorption of dyes from aqueous solutions, Chemical Engineering Journal, 171 (1), 320-327. [DOI:10.1016/j.cej.2011.04.012]
6. Hung-Yee Shu, Ming-Chin Chang, (2005). Decolorization and mineralization of a phthalocyanine dye C.I. Direct Blue 199 using UV/H2O2 process, J. Hazard. Mater. B125: 96-101. [DOI:10.1016/j.jhazmat.2005.05.016] [PMID]
7. Filiz Ay, Ebru Cokay Catalkaya, Fikret Kargi, (2009). A statistical experiment design approach for advanced oxidation of Direct Red azo-dye by photo-Fenton treatment, J. Hazard. Mater. 162: 230-236. [DOI:10.1016/j.jhazmat.2008.05.027] [PMID]
8. A.H. Konsowa, M.E. Ossman , Yongsheng Chen, John C. Crittenden, (2010). Decolorization of industrial wastewater by ozonation followed by adsorption on activated carbon, J. Hazard. Mater. 17: 6181-185.
9. M.A. Behnajady, N. Modirshahla, F. Ghanbary, (2007). A kinetic model for the decolorization of C.I. Acid Yellow 23 by Fenton process,J. Hazard. Mater. 147: 98-102. [DOI:10.1016/j.jhazmat.2007.02.003] [PMID]
10. Menka Surana, Preeti Mehta, Kavita Pamecha, and B.V. Kabra, (2011). Treatment of water contaminated with Reactive Red 198 (RR198) by Photo-Fenton Reagent, Der chemical sinica, 2(2): 177-186.
11. Menka Surana, Preeti Mehta, Kavita Pamecha and B.V. Kabra, (2011). The decolorization and mineralization of azo dye Reactive Yellow 86 in aqueous solution by Photo-Fenton Reagent, Der pharma chemical, 3(2): 39-47.
12. Mohamed M. Ghoneim, Hanaa S. El-Desoky, Naglaa M. Zidan, (2011). Electro-Fenton oxidation of Sunset Yellow FCF azo-dye in aques solutions Original Research Article, Desalination, 274, 1-3: 22-30. [DOI:10.1016/j.desal.2011.01.062]
13. Sanchuan Yu, Meihong Liu, Miao Ma, Ming Qi, Zhenhua Lü, Congjie, (2010). Impacts of membrane properties on reactive dye removal from dye/salt mixtures by asymmetric cellulose acetate and composite polyamide nanofiltration membranes , Journal of Membrane Science, 350: 83-91. [DOI:10.1016/j.memsci.2009.12.014]
14. Yanan Dong, Yanlei Su, Wenjuan Chen, Jinming Peng, Yan Zhang, Zhongyi Jiang, (2011). Ultrafiltration Enhanced with Activated Carbon Adsorption for Efficient Dye Removal from Aqueous Solution Chinese Journal of Chemical Engineering,19: 863-869. [DOI:10.1016/S1004-9541(11)60066-9]
15. Wang, S.; Ang, H.M.; Tade, M.O. (2008). Novel applications of red mud as coagulant, adsorbent and catalyst for environmentally benign processes. Chemosphere 72: 1621-1635. [DOI:10.1016/j.chemosphere.2008.05.013] [PMID]
16. Zidane, F.; Drogui, P.; Lekhlif, B.; Bensaid, J.; Blais, J.-F.; Belcadi, S.; Kacemi, K.E. (2008). Decolorization of dye-containing effluent using mineral coagulants produced by electrocoagulation. J. Hazard. Mater. 155: 153-163. [DOI:10.1016/j.jhazmat.2007.11.041] [PMID]
17. Zhang S.J., Yang M, Yang Q.X., Zhang Y, Xin B.P., Pan F., (2003). Biosorption of reactive dyes by the mycelium pellets of a new isolate of Penicillium oxalicum. Biotechnol Lett. 25(17): 1479-8. [DOI:10.1023/A:1025036407588] [PMID]
18. Bharat Lodha, Sanjeev Chaudhari, (2007). Optimization of Fenton-biological treatment scheme for the treatment of aqueous dye solutions, J. Hazard. Mater. 148: 459-466. [DOI:10.1016/j.jhazmat.2007.02.061] [PMID]
19. M. Perez, F. Torrades, J.A. Garcia-Hortal, X. Domenech, J. Peral, (2002). Removal of organic contaminants in paper pulp treatment effluents under Fenton and photo-Fenton conditions, Appl. Catal. B 36: 63-74. [DOI:10.1016/S0926-3373(01)00281-8]
20. K.H. Chan, W. Chu, (2003). Modeling the reaction kinetics of Fenton's process on the removal of atrazine, Chemosphere 51: 305-311. [DOI:10.1016/S0045-6535(02)00812-3] [PMID]
21. I.A. Balcioglu, I. Arslan, (2005). Partial oxidation of reactive dyestuffs and synthetic textile dye-bathby the O3 and O3/H2O2 processes, Water Sci. Technol. 43: 221-228. [DOI:10.2166/wst.2001.0093]
22. H.Y. Shu, C.R. Huang, (1995). Degradation of commercial azo dyes in water using ozonation and UV enhanced ozonation process, Chemosphere 31: 3813-3825. [DOI:10.1016/0045-6535(95)00255-7]
23. A.M.L. Marechal, Y.M. Slokar, T. Taufer, (1997). Decolorization of chlorotriazine reactive azo dyes with H2O2/UV, Dyes Pigment 33: 281-298. [DOI:10.1016/S0143-7208(96)00057-5]
24. N. Daneshvar, D. Salari, A.R. Khatee, (2003). Photocatalytic degradation of azo dye acid red 14 in water: investigation of the effect of operational parameters, J. Photochem. Photobiol. A 157: 111-116. [DOI:10.1016/S1010-6030(03)00015-7]
25. M. Neamtu, A. Yediler, I. Siminiceanu, A. Kettrup, (2003). Oxidation of commercial reactive azo dye aqueous solutions by the photo-Fenton and Fenton like processes, J. Photochem. Photobiol. A 161: 87-93. [DOI:10.1016/S1010-6030(03)00270-3]
26. Q. Liao, J. Sun, L. Gao, (2009). Degradation of phenol by heterogeneous Fenton reaction using multi-walled carbon nanotube supported Fe2O3 catalysts, Colloids Surf. A 345: 95-100. [DOI:10.1016/j.colsurfa.2009.04.037]
27. Harry Marsh, Francisco redríguez- Reinoso. Activated Carbon, ISBN: 0080444636. Pub. Date: August 2006. pages: 243-248. [DOI:10.1016/B978-008044463-5/50019-4]
28. O. Legrini, E. Oliveros, A. M. Braun, (1993). Photochemical processes for water treatment, Chem. Rev. 93: 671-698. [DOI:10.1021/cr00018a003]
29. J.H. Ramirez, C.A. Costa, L.M. Madeira, G. Mata, M.A. Vicente, M.L. Rojas- Cervantes, A.J. Lopez-Peinado, R.M. Martin-Aranda, (2007). Fenton-like oxidation of orange II solutions using heterogeneous catalysts based on saponite clay, Appl. Catal. B 71: 44-56. [DOI:10.1016/j.apcatb.2006.08.012]
30. A.E. Ahmed, F. Adam, (2007). Effective and selective heterogeneous catalysts from rice husk ash for the benzylation of some aromatics, Micropor. Mesopor. Mater. 103: 284-291.
31. B.G. Kwon, D.S. Lee, N. Kang, J. Yoon, (1999). Characteristic of p-chlorophenol oxidation by Fenton's reagents, Water Res. 33: 2110-2118. [DOI:10.1016/S0043-1354(98)00428-X]
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